[6-(4-Bromophenyl)-2,2′-bipyridine-κ2 N,N′]bis(triphenylphosphane-κP)copper(I) tetrafluoridoborate
نویسندگان
چکیده
The title compound, [Cu(C(16)H(11)BrN(2))(C(18)H(15)P)(2)]BF(4), is composed of one Cu(I) atom, one 6-(4-bromo-phen-yl)-2,2'-bipyridine (L) ligand, two triphenyl-phosphane mol-ecules and one tetra-fluoridoborate anion. The Cu(I) ion is four-coordinated in a distorted tetra-hedral configuration by two N atoms from L and two P atoms from triphenyl-phosphane ligands. In the L ligand, the two pyridine rings are not coplanar; the mean planes making a dihedral angle of 15.3 (5)°. In the crystal, the ions are linked by weak C-H⋯F inter-actions.
منابع مشابه
[6-(4-Bromophenyl)-2,2′-bipyridine-κ2 N,N′](tricyclohexylphosphine-κP)copper(I) tetrafluoridoborate
In the title compound, [Cu(C(16)H(11)BrN(2))(C(18)H(33)P)]BF(4), the Cu(I) atom is three-coordinated in a distorted trigonal configuration by two N atoms from the 6-(4-bromo-phen-yl)-2,2'-bipyridine ligand and a P atom from the tricyclo-hexyl-phosphine ligand. In addition, a weak anion⋯Cu(I) inter-action with a nearest F⋯Cu separation of 2.696 (5) Å is found.
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